Previous months: - 0808(1) - 1003(2) - 1008(1) - 1011(1) - 1204(1)
Any replacements are listed further down
[6] viXra:1204.0075 [pdf] submitted on 2012-04-18 06:01:16
Authors: Sosale Chandrasekhar
Comments: 15 Pages.
The key assumption of activated complex theory (ACT), that the AC is in thermodynamic equilibrium with the reactants, needs to be reconsidered. This is because the formation of the AC is slower than its collapse to product. However, this can be remedied by assuming that the AC is formed in a rapid pre-equilibrium as a thermally activated species, which collapses to products in a slow step involving the diffusion of another AC molecule (or solvent in the case of a unimolecular reaction). This implies a violation of the principle of microscopic reversibility (PMR), as also the relation between standard free energy change and equilibrium constant (ΔGo = -RTlnK). However, it may be argued that not only do these not apply to processes performed irreversibly, but also that irreversibility requires the breakdown of the PMR. Accordingly, catalysts may alter equilibrium constants, and enzymes may regulate biochemical processes in hitherto unsuspected ways.
Category: Chemistry
[5] viXra:1011.0060 [pdf] submitted on 24 Nov 2010
Authors: Omar Yépez
Comments: 12 pages
The hypertorus electron model is applied to the chemical bond. As a consequence,
the bond topology can be determined. A linear correlation is found between the
normalized bond area and the bond energy. The normalization number is a whole number.
This number is interpreted as the Lewis's electron pair. A new electron distribution
in the molecule follows. This discovery prompts to review the chemical bond, as it is
understood in chemistry and physics.
Category: Chemistry
[4] viXra:1008.0016 [pdf] submitted on 7 Aug 2010
Authors: Chun-Xuan Jiang
Comments: 7 Pages.
It has been proved that the 5g = 18 is unstable, the heaviest element that occurs
naturally is uranium with an atomic number of 92 and the island of stability does not
exist using the modified Pauli principle. This is the Book proof.
Category: Chemistry
[3] viXra:1003.0099 [pdf] submitted on 6 Mar 2010
Authors: W. B. Vasantha Kandasamy, Florentin Smarandache
Comments: 126 pages
Industrial Biotechnology is an interdisciplinary topic to which
tools of modern biotechnology are applied for finding proper
proportion of raw mix of chemicals, determination of set points,
finding the flow rates etc., This study is significant as it results
in better economy, quality product and control of pollution. The
authors in this book have given only methods of industrial
biotechnology mainly to help researchers, students and chemical
engineers. Since biotechnology concerns practical and diverse
applications including production of new drugs, clearing up
pollution etc. we have in this book given methods to control
pollution in chemical industries as it has become a great health
threat in India. In some cases, the damage due to environmental
pollution outweighs the benefits of the product.
Category: Chemistry
[2] viXra:1003.0090 [pdf] submitted on 8 Mar 2010
Authors: Florentin Smarandache, V. Christianto
Comments: 9 pages
In this paper, we describe a very simple experiment with distilled water which
could exhibit anomalous potential electrical energy with very minimum preparation
energy. While this observed excess energy here is less impressive than [1][2]
and the material used is also far less exotic than common LENR-CANR experiments,
from the viewpoint of minimum preparation requirement - and therefore
less barrier for rapid implementation--, it seems that further experiments could be
recommended in order to verify and also to explore various implications of this
new proposition.
Category: Chemistry
[1] viXra:0808.0005 [pdf] submitted on 17 Aug 2008
Authors: Talbot Chubb
Comments: 4 pages
On May 22, a special announcement/presentation was
held at Osaka University by Prof. Yoshiaki Arata in the
presence of colleagues, guests, and press. The announcement
of new results took place in Arata Hall, a campus building
named for Prof. Arata, and a demonstration took place in the
Arata-Zhang laboratory room in a nearby research building.
A research paper describing recent results was made available
in Japanese and English versions.
Category: Chemistry
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